In current state of the art, we report a solitary pot green tactic for the synthesis of task-specific CuI nanoparticles (NPs) encapsulated by eco-healthy low value biomass (LVBM) meglumine. The synthesized meglumine encapsulated CuI NPs (Meg-Cu) material was characterized by using various analytical tools, and it was found that CuI NPs (with <100 nm size) were encapsulated by meglumine molecules interacting with −NHMe and −OH functionalities of meglumine.Meg-Cu was utilized marvelously as a catalyst for the creation of 1,2,3-triazole scaffolds....
A simple, straightforward, and energy-efficient greener route for the synthesis of a series of biologically interesting functionalized 1,1-dihomoarylmethane scaffolds has been developed in the presence of meglumine as an efficient and eco-friendly organo-catalyst via one-pot pseudo-three-component reaction at room temperature. Following this protocol, it is possible to synthesize 1,1-dihomoarylmethane scaffolds of an assortment of C–H activated acids such as dimedone, 1,3-cyclohexadione, 4-hydroxy-6-methyl-2-pyrone, 4-hydroxycoumarin, and 1-phenyl-3-methyl-pyrazolone........
The sugar-based deep eutectic solvent (Meg-Su) mediated synthesis has proven to be a highly efficient and environmentally friendly method for the construction of 1,1-dihomoarylmethane scaffolds. Through a systematic exploration of reaction conditions and substrate scope, this study has provided valuable insights into the synthetic potential of DES in organic chemistry.
We have developed novel ChCl-free NaDES from Meglumine and Oxalic acid (Meg-Ox), also we construct a simple, energy-efficient, and practical method for easy access to a wide range of Pyrazolo-pyrido-pyrimidine Derivatives in the presence of Meg-Ox as a green and eco-compatible NaDES.....
In conclusion, we have developed novel Ch-Cl free NaDES from Meglumine and Succinic acid (Meg-Su), also we construct a simple, energy-efficient, and practical method for easy access to a wide range of spiro[indoline-3,9'-pyrazolo[4,3-b]quinoline scaffolds in the presence of Meg-Su as a green and eco-compatible organo-catalyst. The key advantages of present protocol are mild reaction condition, good to excellent yields, operational simplicity, no cumbersome post treatment, clean reaction profile, energy efficiency, and high atom economy, as well as the use of inexpensive and environmentally benign catalyst.
In summary, we developed Cu-free, catalyst-free and aq. EtOH mediated reaction of phenyl sulfonyl acetonitrile, aromatic aldehyde and NaN3 to construct functionalized 4,5-disubstituted 1,2,3-triazole scaffolds. 4,5-disubstituted NH-1,2,3-triazoles with other aldehyde prepared conveniently......
We have developed novel Ch-Cl free NaDES from Meglumine and malonic acid(Meg-Malo), also we construct a simple, energy-efficient, and practical method for easy access to a wide range of pyrano-pyrazolo-quinolinone scaffolds in the presence of Meg-Malo as a green and eco-compatible organo-catalyst.
